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X-14, Automatic Toilet Bowl Cleaner, Blue plus Fragrance-07/19/2018
Products in this Consumer Product Information Database (CPID) are classified based on their composition:
Substances: single chemicals
Preparations: products which contain chemicals that can be easily separated during normal use
Articles: products or product assemblies that do not contain chemicals that can be separated out from the product or assembly under normal or advertised use.
Classification: Preparation
Indicates country where product is sold.
Market: US/CanadaX-14, Automatic Toilet Bowl Cleaner, Blue plus Fragrance eliminates odors while it cleans and freshens with every flush. It not only turns water sparkling blue, it leaves a fresh fragrance throughout the bathroom.
Purpose of product.
Usage: Toilet bowl cleanerStructure such as solid, liquid, aerosol etc.
Form: tabletsDate when validity of Material Safety Data Sheet (MSDS) or Safety Data Sheet (SDS) was last verified.
Date verified: February 13, 2024P.O. Box 308
Budd Lake NJ 07828
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Chemical Composition/Ingredients
The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
Back
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.-
Primary Chemical Name is the standard name assigned to a chemical substance.
ChemicalChemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.REACH COMPLIANCE
EU Hazard Classification Directive 67/548/EECHazard Symbols are used to classify dangerous substances.
Hazard SymbolsRisk Phrases, denoted as a series of numbers preceded by the letter "R" indicate the nature of the special risks, in accordance with Annex III to Directive 67/548/EEC (see Article 23(2)(d) Directive 67/548/EEC). The numbers are separated by either a comma to denote separate statements concerning special risks, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the special risks.
Risk PhrasesSafety Phrases, denoted as a series of numbers preceded by the letter "S" indicating the recommended safety precautions, in accordance with Annex IV to Directive 67/548/EEC. The numbers are separated by either a comma to denote separate statements concerning safety precautions, or an oblique stroke (/) to denote a combined statement, in a single sentence, of the safety precautions.
Safety PhrasesSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).-- 068039-49-6 -- -- -- -- -- 027636-82-4 -- -- -- -- -- 055406-53-6 -- -- -- -- -- 054830-99-8 -- -- -- -- -- 053219-21-9 -- -- -- -- -- 003844-45-9 -- -- -- -- -- 000094-26-8 -- -- -- -- -- 000080-54-6 -- Xn, N -- -- -- -- 000076-22-2 -- -- -- -- -- 000104-54-1 -- -- -- -- -- 008008-57-9 -- -- -- -- -- 008008-56-8 -- -- -- -- -- 068140-00-1 -- 10.0-30.0 -- -- -- -- 000084-66-2 -- -- -- -- -- 006440-58-0 -- -- -- -- -- 008000-48-4 -- -- -- -- -- 000125-12-2 -- -- -- -- -- 004247-02-3 -- -- -- -- -- 000112-53-8 -- -- -- -- -- 000103-26-4 -- -- -- -- -- 000110-41-8 -- -- -- -- -- 000141-43-5 -- Xn, C -- -- -- -- 999999-57-5 -- -- -- -- -- 009004-96-0 -- -- -- -- -- 000057-55-6 -- -- -- -- -- 000144-55-8 -- -- -- -- -- 068955-19-1 -- 5.0-10.0 F, Xi -- -- -- -- 000151-21-3 -- -- -- -- -- 007757-82-6 -- -- -- -- -- 007732-18-5 -- -- -- -- Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.2
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Primary Chemical Name is the standard name assigned to a chemical substance.
Chemical Function Purpose served by this chemical.Chemical Abstracts Service Registry Number is a unique identifier for a chemical and its synonyms. CAS numbers identify the chemical, but not its concentration or specific mixture. CAS Registry Numbers are assigned by the Chemical Abstracts Service, a division of the American Chemical Society. For more information: www.cas.org
CAS No./ID
We have assigned "ID numbers" (with 6 leading zeros or nines, e.g., 000000-xx-x , 888888-xx-x) or 999999-xx-x) for blends and chemicals that do not have CAS numbers.Is a seven-digit number (xxx-xxx-x) assigned by the European Commission to chemicals contained in three inventories:
EC No.
EINECS is the European Inventory of Existing Commercial Substances and its EINECS numbers are displayed as 2xx-xxx-x.
ELINCS is the European List of Notified Chemical Substances that was available after September 18, 1981 and its ELINCS numbers are displayed as 4xx-xxx-x.
NLP is the No-Longer Polymers category and its NLP numbers are displayed as 5xx-xxx-xPercent of chemical in preparation.
% Conc.California Prop.65 Chemical?The GHS is an acronym for The Globally Harmonized System of Classification and Labelling of Chemicals. The GHS is a system for standardizing and harmonizing the classification and labelling of chemicals. Chemicals are associated with codes that define their health, physical and environmental hazards.This universal hazard communication system was developed to ensure that employers, employees and consumers are provided with adequate, practical, reliable and comprehensible information on the hazards of chemicals, so that they can take effective preventive and protective measure for their own health and safety.
UN Global Harmonization Classification
The GHS classifications for chemicals associated with products in this database may be viewed by selecting the "Advanced" button on the Chemical Ingredients tables. Since this is a work in progress, GHS classifications may not be shown for all chemical ingredients.Hazard Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS). There are 4 categories of Hazard Codes:
- Physical Hazard Codes (H200 series)
- Health Hazard Codes (H300 series)
- Environmental Hazard Codes (H400 series)
- Supplementary Hazard Codes (EUH series)
Hazard Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.
Hazard Statement CodePrecautionary Codes and their associated descriptions are an essential part of the Globally Harmonized System of Classification and Labelling of Chemicals (GHS).
Precautionary Code
Precautionary Codes may be found in the "Advanced" version of Chemical Composition / Ingredients tables.PictogramSVHC is a substance (identified by the European Chemicals Agency) that may have serious and often irreversible effects on human health and the environment. SVHC are defined in Article 57 of Regulation (EC) No 1907/2006 (“the REACH Regulation”) and include substances which are:
SVHC?
1. Carcinogenic, Mutagenic or toxic to Reproduction (CMR), meeting the criteria for classification in category 1 or 2 in accordance with Directive 67/548/EEC or in category 1a or 1b in accordance with EC No 1272/2008This directive was recently replaced by the new EU regulation (EC) No 1272/2008.
2. Persistent, Bioaccumulative and Toxic (PBT) or very Persistent and very Bioaccumulative (vPvB) according to the criteria in Annex XIII of the REACH Regulation, or
3. Identified, on a case-by-case basis, from scientific evidence as causing probable serious effects to human health or the environment of an equivalent level of concern as those above (e.g. endocrine disrupters).Endocrine Disruptor (ED)2,4-Dimethyl-3-Cyclohexene Carboxaldehyde
Fragrance
068039-49-6
268-264-1-- No -- -- -- No No 2,4-Imidazolidinedione, (hydroxymethyl)-5,5-dimethyl-
Preservative
027636-82-4
---- No -- -- -- No No 3-Iodo-2-propynylbutylcarbamate
Preservative
055406-53-6
259-627-5-- No -- -- -- No No 3a,4,5,6,7,7a-Hexahydro-4,7-Methano-1h-Inden-5(Or 6)-Yl Acetate
Fragrance
054830-99-8
259-367-2-- No -- -- -- No No 7-Octen-2-ol, 2-methyl-6-methylene-, dihydro deriv.
Fragrance
053219-21-9
258-432-2-- No -- -- -- No No Acid Blue 9
Colorant
003844-45-9
223-339-8-- No -- -- -- No No Butylparaben
Fragrance
000094-26-8
202-318-7-- No H315, H318 P264, P280, P302+P352, P321, P362+P364, P305+P351+P338, P310 Yes H Butylphenyl Methylpropional
Fragrance
000080-54-6
201-289-8-- No H302, H315, H317, H361, H412 P201, P202, P281, P308+P313, P405, P501 Yes No Camphor
Fragrance
000076-22-2
200-945-0-- No H228, H315, H318, H371, H332 P210, P240, P241, P280, P370+P378, P264, P302+P352, P321, P332+P313, P362, P305+P351+P338, P310, P260, P270:, P405, P501, P261, P271, P304+P340,P312 No No Cinnamyl Alcohol
Fragrance
000104-54-1
203-212-3-- No H411, H302, H317 -- No No Citrus Aurantium Dulcis Oil (Orange oil)
Fragrance
008008-57-9
---- No -- -- -- No No Citrus oils
Fragrance
008008-56-8
284-515-8-- No -- -- -- No No Cocamide MEA
Thickener
068140-00-1
268-770-210.0-30.0 No -- -- -- No No Diethyl phthalate
Fragrance
000084-66-2
201-550-6-- No -- -- -- No No DMDM hydantoin
Preservative
006440-58-0
229-222-8-- No H302 P301+P312 No No Eucalyptus Globulus Leaf OilÂ
Fragrance
008000-48-4
283-406-2-- No H226, H304, H315, H317, H411 P210, P233, P240, P241, P242, P243, P261, P272, P273, P280, P301+P310, P302+P352, P303+P361+P353, P331, P333+P313, P363, P391, P403+P235, P405, P501 No No Isobornyl acetate
Fragrance
000125-12-2
204-727-6-- No -- -- -- No No Isobutylparaben
Fragrance
004247-02-3
224-208-8-- No H315, H318 P264, P280, P302+P352, P321, P332+P313, P362+P364, P305+P351+P338, P310 Yes H Lauryl alcohol
Plasticizer
000112-53-8
203-982-0-- No H319, H400, H411 P264, P280, P305+P351+P338, P337+P313, P273, P391, P501 No No Methyl Cinnamate
Fragrance
000103-26-4
203-093-8-- No H317 P261, P272, P280, P302+P352, P333+P313, P363 No No Methylundecanal
Fragrance
000110-41-8
203-765-0-- No H315, H317, H400, H410 P261, P264, P272, P273, P280, P302+P352, P333+P313, P362, P391, P501 No No Monoethanolamine (MEA)
Preservative
000141-43-5
205-483-3-- No H302, H312, H332, H314, H335, H412 P273, P501 No No Non-hazardous ingredient(s)
Withheld as CBI
999999-57-5
---- No -- -- -- No No Polyglycol oleate
Emulsifier
009004-96-0
500-015-7-- No -- -- -- No No Propylene glycol
Solvent
000057-55-6
200-338-0-- No -- -- -- No No Sodium bicarbonate
Detergent
000144-55-8
205-633-8-- No -- -- -- No No Sodium C12-18 fatty alcohol sulfate
Surfactant
068955-19-1
273-257-15.0-10.0 No H315, H318, H412 P280, P302+P352, P305+P351+P338, P310, P321, P332+P313, P362, P273, P501 No No Sodium lauryl sulfate (SLS)
Surfactant
000151-21-3
205-788-1-- No H302, H315, H318, H412 P264, P280, P301+P312, P330, P302+P352, P305+P351+P338, P310, P321, P332+P313, P362, P273, P501 No No Sodium sulfate
Builder
007757-82-6
231-820-9-- No -- P262 -- No No Water
Solvent
007732-18-5
231-791-2-- No -- -- -- No No Click on each chemical for information on chemical structure, properties and health effects.
Click on Chemical, CAS No./ID or EC No. headings to sort values.
Sources for Chemical Classifications- European Commission>JRC>IHCP>European chemical Substances Information System (ESIS) Table 3.1
- European Chemicals Agency, http://echa.europa.eu/
ECHA Disclaimer: http://echa.europa.eu/web/guest/legal-notice
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Hazard Statements
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- Code
- Statement
- H226 : Flammable liquid and vapourH228 : Flammable solidH302 : Harmful if swallowedH304 : May be fatal if swallowed and enters airwaysH312 : Harmful in contact with skinH314 : Causes severe skin burns and eye damageH315 : Causes skin irritationH317 : May cause an allergic skin reactionH318 : Causes serious eye damageH319 : Causes serious eye irritationH332 : Harmful if inhaledH335 : May cause respiratory irritationH361 : Suspected of damaging fertility or the unborn childH371 : May cause damage to organsH400 : Very toxic to aquatic lifeH410 : Very toxic to aquatic life with long lasting effectsH411 : Toxic to aquatic life with long lasting effectsH412 : Harmful to aquatic life with long lasting effects
- P201 : Obtain special instructions before useP202 : Do not handle until all safety precautions have been read and understoodP210 : Keep away from heat/sparks/open flames/hot surfacesP233 : Keep container tightly closedP240 : Ground/bond container and receiving equipmentP241 : Use explosion-proof electrical/ventilating/light/…/equipmentP242 : Use only non-sparking toolsP243 : Take precautionary measures against static dischargeP260 : Do not breathe dust/fume/gas/mist/vapours/sprayP261 : Avoid breathing dust/fume/gas/mist/vapours/sprayP262 : Do not get in eyes, on skin, or on clothingP264 : Wash … thoroughly after handlingP271 : Use only outdoors or in a well-ventilated areaP272 : Contaminated work clothing should not be allowed out of the workplaceP273 : Avoid release to the environmentP280 : Wear protective gloves/protective clothing/eye protection/face protectionP281 : Use personal protective equipment as requiredP310 : Immediately call a POISON CENTER or doctor/physicianP312 : Call a POISON CENTER or doctor/physician if you feel unwellP321 : Specific treatment (see … on this label)P330 : Rinse mouthP331 : Do NOT induce vomitingP362 : Take off contaminated clothing and wash before reuseP363 : Wash contaminated clothing before reuseP391 : Collect spillageP301+P310 : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP301+P312 : IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwellP302+P352 : IF ON SKIN: Wash with soap and waterP303+P361+P353 : IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/showerP304+P340 : IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathingP305+P351+P338 : IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to doP308+P313 : If exposed or concerned: Get medical advice/attentionP332+P313 : If skin irritation occurs: Get medical advice/attentionP333+P313 : If skin irritation or a rash occurs: Get medical advice/attentionP337+P313 : Get medical advice/attentionP370+P378 : In case of fire: Use … for extinctionP405 : Store locked upP501 : Dispose of contents/container to
- GHS02 : FlammableGHS05 : CorrosiveGHS07 : IrritantGHS08 : Health HazardGHS09 : Environmentally Hazardous
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Health Effects Information
Ingredients and Health Effects Information are taken from the manufacturer's product label and/or the Safety Data Sheet (SDS). Products are not tested and manufacturer's information presented here is not evaluated by DeLima Associates.
View Safety Data Sheet(SDS) Date that the Safety Data Sheet (SDS) was issued by manufacturer of a specific product.
SDS DATE :July 19, 2018 Health Flammability Reactivity HMIS is the Hazardous Materials Identification System developed by the American Coatings Association and indicates the levels (“1” to “4”) of Health Hazard, Flammability Hazard and Physical Hazard associated with a specific product.
HMIS RATING2 0 0 -
V.O.C Information
Volatile Organic Compounds %/Wt. With Solvent : 0
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SVHC declaration
Warning: This product contains Substances of Very High Concern (SVHC).
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Warnings
Hazard StatementsWarning. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation..Precautionary statements.GeneralNone.PreventionAvoid breathing dust. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves and eye protection.ResponseIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention.IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice or attention. Take off contaminated clothing and wash before reuse.Storage
None.DisposalDispose of contents and container in accordance with local and national regulations. -
Acute health effects
From SDS
Hazards Identification
Emergency Overview
Warning. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation.
Potential Health Effects
Eye Contact: Direct contact may cause moderate irritation to eyes.
Skin Contact: May cause moderate irritation to skin.
Inhalation: Inhalation is not a normal route of exposure for this product. If dust from product is inhaled irritation of the nose, mouth and upper respiratory tract would be expected. May aggravate existing respiratory conditions such as asthma.
Ingestion: May cause irritation to the mouth and gastrointestinal tract. May cause abdominal pain, nausea and vomiting.
Signs and Symptoms of Exposure: May cause moderate eye and skin irritation. Inhalation of dust may cause nose, throat, and upper respiratory tract irritation. -
Chronic health effects
From SDS
None currently known. -
Carcinogenicity
None of the components are listed as a carcinogen or suspect carcinogen by IARC, NTP, ACGIH or OSHA.
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Handling information
Avoid direct contact with product. Avoid breathing dust from product. Wash thoroughly after use. Keep out of the reach of children.
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Disposal information
Dispose in accordance with federal, state, and local regulations.
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California Prop. 65 Warning
This product does not require a California Proposition 65 warning.
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First Aid
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.Skin Contact: Wash with soap and water for several minutes. Remove contaminated clothing and wash before reuse. If irritation develops and persists, get medical attention.Inhalation (Breathing): First aid is normally not required. If dust from product is inhaled, move to fresh air. Get medical attention if irritation develops and persists.Ingestion (Swallowed): Do not induce vomiting. Rinse out mouth and drink one glass of water if victim is conscious and responsive. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324- 7596
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